So this is a question I actually "know" the answer to (in the sense that I know broadly what the answer is, but I'm missing crucial details and expertise to find an exact unique answer).
A long while ago, someone posed this question to me, and I found that the smallest example of a polyhedron with an odd number of faces where each face is an n-gon is an enneahedron with 4-gon faces. I don't remember where I found this particular assertion but I suspect it might have been on OEIS or something.
At the time I had hunted down a page that had a full explanation and image of this object, but unfortunately it is now a 404.
The motivation for this question is I recently got into a discussion about different rhombuses that appear in various geometrical shapes, and I thought I remembered the 4-gons in this object being rhombuses (however, I might be completely mistaken), and I was wondering after their ratio if they were.
Let $e_i$ be the counts of edge type $i$, $f_i$ the counts of face type $i$ and $n_i$ number of edges of the $i$-th face type. Then you will have $$2\sum e_i=\sum n_i\,f_i$$ Thus, when asking for a single face type (i.e. at the right hand side the sum is breaking down), your quest cannot be solved for any odd $n$, because then $f$ is being forced to be even.
So indeed, the smallest possible value of $n$ within your quest would be 4.
--- rk