Solving a Simple SDE

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I am wondering, does, $F(X) = e^X$ a solution to the problem of

$dX = \mu dt + \sigma dW$?

My understanding of solving SDE is simply start with a guess solution, then expand using Ito's formula, if we can get back the SDE that is being asked, then we are done. But what exactly is the example below demonstrate?

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It seems that you don't have a clear understanding of what is going on. The example is simply an application of the Ito's Formula.

Ito's Formula. Suppose that $X(\cdot)$ has a stochastic differential $$ dX = Fdt+GdW \tag{1} $$ for $F \in L^1(0,T)$, $G \in L^2(0,T)$. Assume $u:\mathbb{R} \times[0,T] \to \mathbb{R}$ is continuous and that $\frac{\partial u}{\partial t}$,$\frac{\partial u}{\partial x}$,$\frac{\partial^2 u}{\partial x^2}$ exist and continuous. $$ Z \overset{define}{=} u(X(t),t) $$ Then $Z$ has the stochastic differential $$\begin{align} dZ &= \frac{\partial u}{\partial t}dt+\frac{\partial u}{\partial x}dX + \frac12 \frac{\partial^2 u}{\partial x^2}G^2dt \\ &= \left(\frac{\partial u}{\partial t}+\frac{\partial u}{\partial x}F+\frac12 \frac{\partial^2 u}{\partial x^2}G^2\right)dt + \frac{\partial u}{\partial x}GdW \tag{2} \end{align} $$

In your example, $F = \mu$, $G=\sigma$, and $Z =u(X(t),t)= e^X$. The partial derivatives are computed as $$ \frac{\partial u}{\partial t} = 0, \quad \frac{\partial u}{\partial x}=e^X=Z, \quad \frac{\partial^2 u}{\partial x^2}=e^X=Z $$ Substitute into the equation (2), one gives $$ \begin{equation} dZ= \left(0+\mu Z+\frac12 \sigma^2Z\right)dt + \sigma ZdW = \left(\mu +\frac12 \sigma^2\right)Zdt + \sigma ZdW \tag{3} \end{equation} $$ If $Z$ is a solution, we should have $$ \mu = \left(\mu +\frac12 \sigma^2\right)Z\quad \text{and}\quad \sigma = \sigma Z $$