Solving an Improper Integral: $\int_0^\infty r^2 e^{-a\cdot r}dr$

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I have an improper integral as follows:

$$\int_0^\infty r^2 e^{-a\cdot r}dr.$$

I try to evaluate it by parts and get $ [ -(\dfrac{r^2}{a} + \dfrac{2r}{a^2} + \dfrac{2}{a^3}) \cdot e^{-a \cdot r} ]^\infty_0 $, which leads me to nowhere.

According to the given solution, this integral can be solved like this:

$\int_0^\infty r^2 e^{-a\cdot r} = \dfrac{\delta^2}{\delta r^2} \int_0^\infty e^{-a\cdot r} = ... = \dfrac{2}{a^3} $

Which rule did they apply here (for the derivative)?

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OK, made a mistake for the second method (apologies): For the second method you have to consider $$I(a) = \int_0^\infty e^{-a\cdot r} \, dr$$ Then if you look at $\frac{\partial^2 }{\partial \, a^2} I(a)$ this is equal to the required integral. But you have $I(a)= \frac{1}{a}$ and you can easily work out $\frac{\partial^2 }{\partial \, a^2} \frac{1}{a}$. As an additional point, you can't really look at $\frac{\partial^2 }{\partial \, r^2} \int_0^\infty r^2 e^{-a\cdot r} \, dr$, since $r$ is an integration variable.

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Hint...if you evaluate the expression you found, rather than leading you "nowhere" you get the same answer as given in the alternative solution. This is because $$x^ne^{-x}\rightarrow0$$ as $x\rightarrow\infty$

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Method 1. One may integrate by parts twice as follows, $$ \begin{align} \int_0^\infty r^2 e^{-a\cdot r}dr&=\left[ r^2\:\frac{e^{-a\cdot r}}{-a}\right]_0^\infty+\frac1a\int_0^\infty (2r)\: e^{-a\cdot r}dr \\\\&=0+\frac{2}a\int_0^\infty r\: e^{-a\cdot r}dr \\\\&=\frac{2}a\left(\left[ r\:\frac{e^{-a\cdot r}}{-a}\right]_0^\infty+\frac1a\int_0^\infty e^{-a\cdot r}dr\right) \\\\&=\frac{2}a\left(0+\frac1a\cdot \frac1a\right) \\\\&=\frac{2}{a^3} \end{align} $$ where we have used that, for any fixed real numbers $n$ and $a>0$, $$ \lim_{r \to \infty}\left(r^n \cdot e^{-a\cdot r}\right)=0. $$

Method 2. One may apply the Leibniz integral rule twice (all conditions are OK here): $$\frac{d}{da} \left ( \int_\alpha^\beta f(a,x) \,\mathrm{d}x \right )= \int_\alpha^\beta \frac{\partial}{\partial a}f(a,x) \,\mathrm{d}x,$$ on the one hand, $$\frac{d^2}{da^2} \left (\int_0^\infty e^{-a\cdot x} \,\mathrm{d}x \right )= \int_0^\infty \frac{\partial^2}{\partial a^2}e^{-a\cdot x} \,\mathrm{d}x=\int_0^\infty x^2 \cdot e^{-a\cdot x} \,\mathrm{d}x$$ on the other hand, $$\frac{d^2}{da^2} \left (\int_0^\infty e^{-a\cdot x} \,\mathrm{d}x \right )= \frac{d^2}{da^2} \left (\frac1a\right )=\frac{2}{a^3}.$$