In what paper do Hardy and Littlewood first mention, specifically, their 2nd conjecture? It is not mentioned specifically in Partitio Numerorum III.
This conjecture is usually expressed as
$$\pi(x+y)\leq \pi(x)+\pi(y). $$
in which $\pi(x)$ is the number of primes not exceeding $x.$
See, for example, Mathworld's note.
Hardy-Littlewood's second conjecture does appear in the paper you cite.$^*$
The article is 70 pages long and the idea is briefly noted at pp. 52-54. The article is cited for Hardy-Littlewood's second conjecture in dozens of places and fortunately one gave the pages.
At page 52 the authors introduce a difference.
And on page 54 they conjecture:
At page 68, after related digression, the authors give a calculation and re-state their sense that the conjecture appears plausible.
This conjecture, unlike quite a few others, is not named in the paper as far as I can tell. The usual statement of Hardy-Littlewood's second conjecture is
$$\pi(n+x) \leq \pi(n)+\pi(x).$$
$^*$ G.H Hardy and J.E. Littlewood, Some problems of ‘partitio numerorum:’ III: On the expression of a number as a sum of primes, Acta Mathematica, December 1923, Volume 44, pp.1-70. The full text of the paper is available via Springer. There is a paywall so I cannot link to it. The first five pages are available free at several sites.