Is it true that $k$ is a splitting field of $S_n$ if and only if the characteristic $p$ of $k$ is zero or larger than $n$? The fact that the character table (over $\mathbb C$) has only integer entries smaller or equal to $n$, seems to imply this, or am I mistaken? If the statement is true, could someone give a citation?
Edit: $k$ is a splitting field of $S_n$ if the $k$-algebra $kS_n$ splits over $k$, i.e. if for every simple ($=$ irreducible) $kS_n$-left-module $M$, we have $\mathrm{End}_{kS_n}(M) \cong k$.
The irreducible $S_n$-modules are all realizable over the integers. Specifically, there is a family of $\mathbb{Z} S_n$-modules $S^\lambda$ indexed by partitions $\lambda$ of $n$, called Specht modules, together with symmetric $\mathbb{Z}$-bilinear forms, such that over a field $k$, the quotient by the radical of the form is either zero or irreducible, and the set of non-zero irreducibles obtained this way is a complete set of representatives for the isoclasses of irreducibles. What is true is that the group algebra is semisimple exactly if the characteristic $p$ is bigger than $n$. In general, the blocks are in bijection with the set of $p$-cores of partitions of $n$.
You can read about this in chapter 4 of James' book "The representation theory of the symmetric group".