My question (Abstractly)
If we know how to write the matrix representation of the fundamental representation of SU(N), could we use them to derive the matrix representation of other representations of SU(N)? (adjoint, anti-symmetric, or symmetric, etc.)
For example, for SU(2), I asked a trial question here SU(2) Lie algebra: Derive the 3-dimensional adjoint matrix representation, from the given 2-dimensional fundamental matrix representation.
Now we aim to consider the SU(5) example.
We know the tensor product of 5-dimensional fundamental representation of SU(5) gives the 10-dimensional (anti-symmetric) representation and 15-dimensional (symmetric) representation of SU(5): $$ 5 \times 5 = 10_A + 15_S $$
It is easy to write down the 5-dimensional matrix representations of SU(5) with 24 Lie algebra rank-5 matrix generators as:

My question (Concretely)
is that based on the fact of $$ 5 \times 5 = 10_A + 15_S $$
How do we write down the 10-dimensional and 15-dimensional matrix representations of SU(5)?
10-dimensional matrix representations of SU(5) with 24 Lie algebra rank-10 matrix generators.
15-dimensional matrix representations of SU(5) with 24 Lie algebra rank-15 matrix generators.
Warning: Note that the $10_A$ is not just the rank-5 antisymmetric matrix as Lie algebra generators because that only gives 10 such matrices which generate the SO(5) instead of SU(5).
If $V$, $W$ are representations of some Lie algebra $\mathfrak{g}$ then $V\otimes W$ is a representation with action given by:
$$ X(v\otimes w) = X(v) \otimes w + v \otimes X(w),$$
for each $X \in \mathfrak{g}$. You have the action of $\mathfrak{g} = \mathfrak{su}(5)$ given in some explicit basis $v_1,\dots,v_5$ of $V$ and then you are asking what the action looks like on $V \otimes V$. The simplest basis to pick would perhaps be $v_i \otimes v_j$ for each $i$ and $j$ and you could explicitly calculate what each of your generators does to each of these and you have a series of 25 by 25 matrices (blegh).
However, as you have noted the representation splits up into 2 irreducible representations so perhaps we can do better. What's going on here? Well the action of the Lie algebra commutes with the action of of the symmetric group (i.e. with swapping the order of $v_i \otimes v_j$) so $\bigwedge^2V$, the exterior square, and $\mathrm{S}^2V$, the symmetric square, have to be subrepresentations. These are respectively the spans of $v_i \wedge v_j$ and $v_i \odot v_j$ where we're thinking of these as:
$$v_i \wedge v_j = v_i \otimes v_j - v_j \otimes v_i$$ $$v_i \odot v_j = v_i \otimes v_j + v_j \otimes v_i$$
The exterior square has dimension 10 in this case and the symmetric square has dimension 15.
Now we have to be a little careful here as we are working with $\mathfrak{su}$ which is a real Lie algebra thought of as acting on a complex vector space.
For higher tensor powers we have the same ideas except there are more subrepresentations obtained by looking at the action of the symmetric group. We refer to this as Pleythism and this where Young tableaux and Clebsh-Gordon coefficients pop up to keep track of this.