There is the following result:
Let $X,Y$ be normed spaces. Then the map $T \mapsto T^*$ is an isometric isomorphism from $B(X,Y)$ into $B(Y^*, X^*)$.
I want to show the map $T \mapsto T^*$ is not necessarily onto. In order to do so, I consider the Banach spaces $B(\mathbb{F}, c_0)$ and $B(c_0^*, \mathbb{F}^*)$ and want to show that there is no continuous map $T \mapsto T^*$ from $B(\mathbb{F}, c_0)$ onto $B(c_0^*, \mathbb{F}^*)$. That is, there is an operator in $B(c_0^*, \mathbb{F}^*)$ that is not the adjoint of an operator in $B(\mathbb{F}, c_0)$.
Hint/check:
$B(\mathbb F, c_0)$ is isometric to $c_0$,
$B(c_0^* ,\mathbb F^*)$ is isometric to $c_0^{**}$,
Under this identification, the mapping $T\mapsto T^*$ can be treated as the canonical embedding $c_0 \to c_0^{**}$.
Key word: Reflexive Banach space