Lie group $SO(4)$ is doubly covered by $SU(2) \times SU(2)$, I want to know the map from $SU(2) \times SU(2)$ to $SO(4)$.
The map from $SU_{2}$ to $SO(3)$ is $\begin{pmatrix} \alpha & \beta \\-\overline{\beta} & \overline{ \alpha} \end{pmatrix} \longrightarrow \begin{pmatrix} \frac{1}{2}(\alpha^{2}-\beta^{2}+\overline{\alpha}^{2}-\overline{\beta}^{2} & \frac{i}{2}(-\alpha^{2}-\beta^{2}+\overline{\alpha}^{2}+\overline{\beta}^{2} & -\alpha\beta-\overline{\alpha}\overline{\beta}\\\frac{i}{2}(\alpha^{2}-\beta^{2}-\overline{\alpha}^{2}+\overline{\beta}^{2} & \frac{1}{2}(\alpha^{2}+\beta^{2}+\overline{\alpha}^{2}+\overline{\beta}^{2} & -i(\alpha\beta-\overline{\alpha}\overline{\beta})\\ \alpha\overline{\beta}+\overline{\alpha}\beta & i(-\alpha\overline{\beta}+\overline{\alpha}\beta)& \alpha\overline{\alpha}-\beta\overline{\beta} \end{pmatrix}.$ Therefore what is the image of
$(\begin{pmatrix} \alpha & \beta \\-\overline{\beta} & \overline{ \alpha} \end{pmatrix},\begin{pmatrix} \alpha' & \beta' \\-\overline{\beta}' & \overline{ \alpha}' \end{pmatrix})\in SU_{2}\times SU_{2}$
Here's a sketch of the construction; I'll leave the (more or less straightforward) algebraic details to the reader.
Let $\Bbb V$ be the $4$-dimensional (real) vector space of complex $2 \times 2$ matrices $z \in M(2, \Bbb C)$ satisfying $$z^* = J z^{\top}J^{-1}, \qquad J := \pmatrix{0&-1\\1&0} .$$
Now, realize $SU(2)$ as the group of matrices $g \in M(2, \Bbb C)$ that satisfy $g^*g = \Bbb I$, and define an action of $SU(2) \times SU(2)$ on $\Bbb V$ by $$(g, h) \cdot z := g z h^* .$$ This action preserves the positive-definite bilinear form $$\langle z, w \rangle := \operatorname{Re}\operatorname{tr}(z w^*)$$ on $\Bbb V$ and so defines a map $SU(2) \times SU(2) \to SO(\Bbb V) \cong SO(4)$; this is the desired double cover.
Computing in a basis for $\Bbb V$---the basis $\left(\pmatrix{1&0\\0&1}, \pmatrix{i&0\\0&-i}, \pmatrix{0&1\\-1&0}, \pmatrix{0&i\\i&0}\right)$ is both convenient for computation and (up to an overall rescaling) orthonormal with respect to the bilinear form---gives an explicit formula analogous to that for the map $SU(2) \to SO(3)$ in the question statement.
For more details and similar constructions of the other sporadic coverings among Lie groups (both complex and real), see Paul Garrett's useful notes Sporadic isogenies to orthogonal groups [pdf].