Let $T$ be a tree with maximum degree $\Delta(T)$, and let $\beta'(T)$ denote the size of the minimum edge cover of $T$. The question is to prove that $\beta'(T) \ge \Delta(T)$.
I started by proving that each tree has at least $\Delta(T)$ using induction on $n$. Then I tried using the fact that if we take the edge connected to each leaf then we will have minimum edge coverage equal to $\Delta(T)$ in case all the leaves are connected to the vertex of max degree, if not, then we need at least one more edge. Does it make sense?
In the case where there is only one vertex of maximum degree in $T$, and it's adjacent to all other vertices, you are right that $\beta'(T) = \Delta(T)$, and we can prove this by looking at the edges that cover each of the other vertices.
In other cases, you claim that we need at least one more edge. First of all, this is not always true: we could have a tree that looks like
and this is still possible to cover with $5$ edges. Whether true or false, it needs more proof. You are probably thinking something like "if we take the edge cover we were using previously, which consisted of all the edges incident to the maximum-degree vertex, then that doesn't work anymore and it needs one more edge". But that doesn't mean there's not some more clever strategy, which doesn't start with that edge cover to begin with.
There are two strategies that you could pursue: