I would like someone to review my understand of why the relation "is less than" ($<$ ) is anti-symmetric on $\mathbb{Z}$. My reasoning is as follows:
Anti-Symmetry says that, if $(a,b) \in R$ and $(b, a) \in R$, then $a = b$.
In this case, we cannot have $a < b$ and $b < a$, so we cannot even get to the point where a violation of the condition of anti-symmetry is possible. And so, by default, the relation is anti-symmetric, despite the fact that it contains no elements $(a,b) \in R$ and $(b, a) \in R$ such that $a = b$.
I would appreciate it if people could please take the time to review my reasoning.
You have the defnition of "antisymmetric" wrong. It's not speaking of whether $(a,b)$ and $(b,a)$ are in $\mathbb Z\times\mathbb Z$, but whether they are in the relation that you're asking whether is antisymmetric. In this case that is the less-than relation.
That being said, you're right that $(<)$ is vacuously antisymmetric, for the reason you give in: There's nothing to contradict it, and a "for all" property is true whenever there's no counterexample.