I solved this question this way.
First, there are two ways that the cards will not be alternating:
B - R - B - R - B - R
R - B - R - B - R - B
Second, there are 6! (720) possible orders in which the cards can be dealt.
So, the answer is 2/720. Is this correct?
Without loss of generality, the first card is blue. Then choose a red one with probability $\frac{3}{5}$, a blue one with probability $\frac{2}{4}=\frac{1}{2}$, a red one with probability $\frac{2}{3}$, and the last blue one with probability $\frac{1}{2}$, followed by the last red one. The result is $\frac{2}{5}\cdot(\frac{1}{2})^2=\frac{1}{10}$.