We have:
$z_1 = 2 + 2i$ and $z_2 = -1 -\sqrt{3} i$
I am asked for obtaining arg$\left(\frac{z_1}{z_2}\right)$ and arg($z_1z_2$)
As we know:
$$\theta = \tan^{-1} \left(\frac{y}{x}\right)$$
The division of complex numbers is:
$$\frac{z_1}{z_2} = z_1z_2^{-1} = \frac{z_1z_2^*}{z_2z_2^*}$$
Doing so I got $\frac{\sqrt{3}-1}{-1-\sqrt{3}}$ but I do not know how to get the angle without calculator using this result.
The same happened to me in the product:
$$arg(z_1z_2) = \tan^{-1}\left(\frac{-1-\sqrt{3}}{-1+\sqrt{3}}\right) = ...$$
I know it has to be a silly thing but I am stuck here.
You can try proving by yourself that:
$$ \arg(z_1z_2)=\arg(z_1)+\arg(z_2) $$
Which by extension yields: $$ \arg(z_1/z_2)=\arg(z_1)-\arg(z_2) $$
In your case: $$ \arg(z_1/z_2)=45°-230°=-185° $$