Let $n \in \mathbb{N}$
True or false? For all $A,B \in \mathbb{R}^{n \times n}$ we have that $\det(A+B) \neq \det(A)+ \det(B)$.
The statement should be false because whenever we get that $\det(A) =0$ and $\det(B) =0$, we will have that $\det(A+B) = \det(A) + \det(B)$.
More specific counter-example, let $n = 0$.
Is it alright like that or is my reasoning wrong?
Your reasoning is right, but you can not fix $n=0$ if you want to prove the statement is false for all $n$.
You are right when you say a counter-example is sufficient.
For example, take the null matrix $A$ of $\mathbb R^{n\times n}$, and $B:=A$.
You have $\det(A+B)=0=\det (A)+\det(B)$, so the statement is false.