This was in the book I was studying from so I went to prove it just for the sake of further understanding it, although it wasn't an exercise so I can't really go anywhere to check if my proof is correct. This is my first time working with equivalent relations so I'd really like to get some insight.
Two elements of the quotient $S/{\sim}$ are equal if and only if the corresponding elements in $S$ are related by $\sim$.
Let $A,B,a,b \in S$, and \begin{align*} S/{\sim} \ &:= \{[A]_\sim , \ [B]_\sim, \ \dots \},\\ [A]_\sim \ &:=\{ a \in S \mid a \sim A\},\\ [B]_\sim \ &:=\{ b \in S \mid b \sim B\}. \end{align*}
If $a \sim A$, $b \sim B$, and $a \sim b$, then because $\sim$ is transitive and symmetric, $a \sim b \to a \sim B$ so $a \in [B]_\sim$ and $b \sim a \to b \sim A$ so $b \in [A]_\sim$.
What do you guys think?
Well, you are heading the right way. This is how I will do it, first let's translate into maths your statement:
Now we can just work with your definitions.