Consider the class of well-orderings $W$. Although that class is not first-order axiomatizable, it has an associated first order theory $Th(W)$. Is it finitely axiomatizable? I conjecture that, in addition to the axioms for linear orders, all you need are the axiom that there is a minimum element, and that every element except the last if there is one has an immediate successor. Is this true, or do you need a bit more, or in fact do you need infinitely more?
My second question is, can someone exhibit a model of the first-order theory of well ordered sets that is not itself a well-ordering?
Re: the second question there's a very concrete example: a standard exercise using Ehrenfeucht-Fraisse games is to show that $\mathbb{N}\equiv\mathbb{N}+\mathbb{Z}$. In particular, since $\mathbb{N}$ is a well-ordering, we have $\mathbb{N}+\mathbb{Z}\models Th(W)$.
Re: the first question, your guess is correct: any linear order with a least element and such that all but possibly one element has a successor is a model of $Th(W)$. This can be proved via Ehrenfeucht-Fraisse games as well, and of course yields many more concrete examples of non-well-ordered models of $Th(W)$, but is significantly more complicated.