I need easy examples of unbounded open and connected subsets of $\mathbb{R}^n$ with finite Lebesgue measure.
The example that I have in mind belongs to the class of examples which are easy to draw but longer to write down (imagine a countable family of open balls in the plane whose radius decreases as $1/n$, the centers move towards infinity but with a velocity that preserves the overlap so that the connectedness is maintained).
There clearly is no such example if $n=1$.
For $n=2$ a simple example would be $\{(x,y):|y|<1/(x^2+1)\}$. You could give an analogous example for $n>2$.
Now it turns out that "I need easy examples of unbounded open and connected subsets of $\mathbb{R}^n$ with finite Lebesgue measure." is not what the OP actually wanted; he says "It is interesting to me to understand under which conditions on a metric measure spaces a connected open set is bounded if and only if it has finite measure."
Of course it's trivial to concoct a condition C such that C implies there is an unbounded connected open set of finite measure. The C I have in mind seems unreasonably strong to me, making the proof trivial, but I suspect it nonetheless holds in all the metric measure spaces the OP has in mind:
Regarding my comment on whether that condition is unreasonably strong or not: Imagine a path in the plane. Of course that path can have positive two-dimensional Lebesgue measure. If you're the sort of person who thinks of a path in the plane with positive area as rare or pathological then the conditions in the triviality seem quite reasonable. Otoh if you're me you think that a "typical" path in the plane has positive measure, so the triviality seems quite weak, having unreasonably strong hypotheses. (Otoh assuming every ball is connected and has finite measure seems perfectly reasonable; certainly not necessary, but the sort of thing you'd expect to have to assume.)
Note to be clear, when I say there exists a path from $x$ to $y$ of measure $0$ I mean there exists a continuous $\gamma:[0,1]\to X$ with $\gamma(0)=x$, $\gamma(1)=y$, and $\mu(\gamma([0,1])=0$; in particular the measure of the path $\gamma$ is $\mu(\gamma([0,1])$.
Proof. Say $(x_n)$ is a sequence with $d(x_n,x_0)\to\infty$. Say $\gamma_n$ is a path from $x_n$ to $x_{n+1}$ of measure zero. Let $K_n=\gamma_n([0,1])$. For $r>0$ let $$V_n(r)=\bigcup_{p\in K_n}B(p,r).$$Now $K_n$ is compact, so $$\bigcap_{r>0}V_n(r)=K_n.$$And $V_n(1)$ is bounded, so $\mu(V_n(1))<\infty$, hence $$\lim_{r\to0}\mu(V_n(r))=\mu(K_n)=0.$$So you can choose $r_n>0$ such that $\mu(V_n(r_n))<1/n^2$, and now $$V=\bigcup_{n=0}^\infty V_n(r_n)$$is an unbounded connected open set with finite measure.
Note for anyone who detects a whiff of snarkiness here: It's irritating when someone posts a question, and then comments on an answer saying that's not what (s)he wanted! It wastes people's time. If "I need easy examples of unbounded open and connected subsets of $\mathbb{R}^n$ with finite Lebesgue measure." was really what the OP wanted then the first two sentences of this post would have made him happy - those two sentences give a much "easier" example of what he said he wanted.