The symmetric group is the set of all permutations.
My question addresses the representability of the symmetric group using only additions. I am guessing that on the finite field $\mathbb{Z}/n \mathbb{Z}$ by defining a "Cartesian" basis $(1,0,,0,...),(0,1,0...),...$
Could we then say that the symmetric group is isomorphic to the abelian group?
You are mixing up a few concepts here.
All of the groups $\mathbb Z$, $\mathbb Z/n\mathbb Z$, $\mathbb Z^n$ and $\prod_{i=1}^\infty \mathbb Z$ are abelian, since the addition in $\mathbb Z$ is commutative.
The symmetric group $S_n$ is abelian only for $n=1,2$. As soon as you have at least 3 elements, you can define bijective maps like \begin{align} \sigma : [3] &\to [3] & \rho : [3] &\to [3]\\ 1 &\mapsto 2 & 1&\mapsto 1 \\ 2 &\mapsto 1 & 2&\mapsto 3 \\ 3 &\mapsto 3 & 3&\mapsto 2, \end{align} where $\sigma$ swaps $1$ and $2$ (often written $\sigma=(12)$, using cycle notation), and $\rho$ swaps $2$ and $3$ ($\rho=(23)$). I leave it to you to check that $\sigma\circ\rho \neq\rho\circ\sigma$. This shows that $S_n$ is not abelian when $n\ge 3$. In particular it is not isomorphic to any of the abelian groups mentioned above.
The only non-trivial abelian symmetric group is $S_2$, it is in fact isomorphic to $\mathbb Z/2\mathbb Z$, since there is only one possible group operation on a set with $2$ elements.