I am currently trying to understand the derivation of the Gamma function, namely, this step
$$ \begin{align}\int ^\infty _0 (- \exp(-y))'& y^{\alpha -1} \,\mathrm dy \\&= - \exp(-y) y^{\alpha -1} | ^ \infty _ 0 + (\alpha -1 )\int ^\infty _0 (- \exp(-y))' y^{\alpha -2} \,\mathrm dy \\&= (\alpha -1) \Gamma (\alpha -1)\end{align} $$
Namely, in the second step, how does one conclude that $ \exp(-y) y^{\alpha -1} | ^ \infty _ 0 = 0$ ?
Based on what you wrote, you tacitly assumed $\alpha > 1$, therefore your problem boils down to show that $$\lim_{y \to \infty} \frac{y^{\alpha - 1}}{e^y} = 0,$$ which is a classic result. There are multiple ways to prove this, one way is to notice that $$ e^{y} = 1 + y + \frac{y^2}{2!} + \cdots > \frac{y^{\lfloor \alpha \rfloor}}{\lfloor \alpha \rfloor!},$$ then apply the squeeze principle.