In a negative feedback loop i understand the mistake of canceling unstable poles. But take for example a plant
$G(s)=\frac{1}{s+1}$
and an I-control
$F(s)= \frac{1}{s}$
Then the system has the transfer function
$T(s)= \frac{FG}{1+FG}=\frac{\frac{1}{s}}{(s+1)+\frac{1}{s}}$
My question is: Is it valid to cancel s=0 poles? so that system becomes
$T(s)= \frac{1}{s^2 +s +1}$
Or does it go against cancelling unstable poles?
Do not ever cancel poles. You will affect observability and/or controllability. Unstable poles are even worse. Bibo stability of a zero depends on its order.
I dont see any pole cancellation in your example.
In practice you always use PI, never I on its own.