Given a Hilbert space $\mathcal{H}$.
Consider a free Hamiltonian $H_0$ and a perturbed one $H$.
Introduce the wave operators: $$\Omega^\pm(H,H_0):=\mathrm{s-lim}_{\tau\to\pm\infty}e^{i\tau H}e^{-i\tau H_0}P_\text{ac}(H_0)$$ (The existence being implicitely assumed!)
Why do we restrict to the absolutely continuous subspace?
(Would it work for the singular continuous subspace, too, or is it because of Riemann-Lebesgue?)
This following bits comes out of Reed and Simon Vol III, and I think this helps explain the problem. You should own Vol II and Vol III if you're seriously interested in this topic.
This definition is followed immediately by