Let $p\left(n\right)$ be $1$ if $n$ is a prime, and $0$ otherwise. Recall the prime divisor function.
$$w\left(n\right)=\sum_{d\mid n}p\left(d\right)$$
By the Möbius inversion formula, we have
$$p\left(n\right)=\sum_{d\mid n}w\left(d\right)\mu \left(\frac{n}{d}\right)$$
Let's write the prime counting function with this.
$$\begin{align} \pi \left(n\right) &= \sum_{t\leq n}p\left(t\right) = \sum_{t\leq n}\sum_{d\mid t}w\left(d\right)\mu \left(\frac{t}{d}\right)\\ &= \sum_{t\leq n}\sum_{ab=t}w\left(a\right)\mu \left(b\right) = \sum_{ab\leq n}w\left(a\right)\mu \left(b\right)\\ &= \sum_{a\leq n}w\left(a\right)\sum_{b\leq \frac{n}{a}}\mu \left(b\right) = \sum_{a\leq n}w\left(a\right)M\left(\frac{n}{a}\right) \end{align}$$
Where $M$ is the Mertens function.
The twin prime counting function is
$$\begin{align} \pi _{2}\left(n\right) &=\sum_{t\leq n}p\left(t\right)p\left(t+2\right) = \sum_{t\leq n}\left(\sum_{d\mid t}w\left(d\right)\mu \left(\frac{t}{d}\right)\right)\left(\sum_{d\mid t+2}w\left(d\right)\mu \left(\frac{t+2}{d}\right)\right)\\ &= \sum_{t\leq n}\sum_{\left(d_{1}\mid t,d_{2}\mid \left(t+2\right)\right)}w\left(d_{1}\right)w\left(d_{2}\right)\mu \left(\frac{t}{d_{1}}\right)\left(\frac{t}{d_{2}}\right) = \sum_{t\leq n}\sum_{\left(ab=t,cd=t+2\right)}w\left(a\right)w\left(c\right)\mu \left(b\right)\mu \left(d\right)\\ &= \sum_{\left(ab\leq n,cd\leq n+2\right)}w\left(a\right)w\left(c\right)\mu \left(b\right)\mu \left(d\right) \end{align}$$
If we use same transformations, we have
$$\pi _{2}\left(n\right)=\sum_{\left(a\leq n,cd\leq n+2\right)}w\left(a\right)w\left(c\right)\mu \left(d\right)\sum_{b\leq \frac{n}{a}}\mu \left(b\right)=\sum_{\left(a\leq n,cd\leq n+2\right)}w\left(a\right)w\left(c\right)\mu \left(d\right)M\left(\frac{n}{a}\right)$$
Eventually this comes up.
$$\pi _{2}\left(n\right)=\sum_{\left(a\leq n,c\leq n+2\right)}w\left(a\right)w\left(c\right)M \left(\frac{n+2}{c}\right)M\left(\frac{n}{a}\right)=\sum_{a\leq n}w\left(a\right)M\left(n/a\right)\sum_{a\leq n+2}w\left(a\right)M\left(\frac{n+2}{a}\right)=\pi \left(n\right)\pi \left(n+2\right)$$
Which is nonsense. What am I doing wrong?
$$\begin{align} \pi _{2}(n) &=\sum_{t\leq n}p(t)p(t+2)\\ &=\sum_{t\leq n}(\sum_{d\mid t}w(d)\mu (\frac{t}{d}))(\sum_{d\mid t+2}w(d)\mu (\frac{t+2}{d}))\\ &=\sum_{t\leq n}\sum_{(d_{1}\mid t,d_{2}\mid (t+2))}w(d_{1})w(d_{2})\mu (\frac{t}{d_{1}})\underbrace{(\frac{t}{d_{2}})}_{\mu\left(\frac{t+2}{d_2}\right)}\tag{Typo}\\ &=\sum_{t\leq n}\sum_{(ab=t,cd=t+2)}w(a)w(c)\mu (b)\mu (d)\\ &=\sum_{(ab\leq n,cd\leq n+2)}w(a)w(c)\mu (b)\mu (d)\tag{Error} \end{align}$$
Not going into the typo, which anyway is corrected in the next line, the last line is the big mistake. You dropped the condition that $cd - ab = 2$, and that produces a lot of additional terms that shouldn't be there.