A classic linear algebra example of isomorphism is that $\mathbb{P}_n^\mathbb{F}$, the set of polynomials of degree at most $n$ over a field $\mathbb{F}$, is isomorphism to $\mathbb{F}^{n+1}$. The idea of an isomorphism is that most (all?) relations and properties carry over from one to the other, and vice versa. But consider the aspect of solving an equality of two polynomials in $\mathbb{P}_n^\mathbb{F}$ (with set, predefined coefficients). I can't seem to think of any equivalent action in $\mathbb{F}^{n+1}$.
Is there an equivalent action there, or is there no analogy? If there is a relation, is it common to use geometric intuitions on $\mathbb{F}^{n+1}$ to make claims about solving relations with polynomials in $\mathbb{P}_n^\mathbb{F}$?
Polynomials have more structure than just that of a vector space. Namely, the space $\mathbb{P}$ of polynomials is not only a vector space, but rather a ring, or even more an algebra. This algebra has a normed ring structure, given by degree.
Solving a polynomial equation is more related to the multiplicative structure of $\mathbb{P}$, that is, finding monomials which divide a given polynomial.
So to answer your question: no, there is no good analogue of "solving a polynomial equation" in $\mathbb{F}^n$.
On the other hand, the isomorphism you mentioned is usually given by $a_0+a_1x+\cdots+a_nx^n\mapsto(a_0,\ldots,a_n)$, and the coefficients of a polynomial may give some information about how to find a root, e.g. with the rational root theorem. But this result is not usually proved based on the vector space structure of $\mathbb{F}^{n+1}$, so this is not a good analogy.