Should I read it literally? Or does it mean that the multiplicative identity on the left hand side is not equal to the additive identity on the right hand side?
What does the notation of “1=/= 0” mean for “Let R be a ring with unity 1=/= 0”?
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On
It means $1\neq 0$, when people can't format well.
As usual, $0$ is what we call the additive identity of the ring and $1$ is what we call the multiplicative identity. There is a ring where $1=0$, it's just that it's the trivial ring $\{0\}$. This excludes that.
On
It mean that $R$ is a ring and that the neutral element of $+$ is different that the neutral element of the multiplication.
On
There does exist a ring where $1=0$. In fact, there's a single such ring, for if $1=0$ then for any $x \in R$ we have $x\cdot 1 = x \cdot 0 \Rightarrow x=0$. So, zero is the only element of this ring.
As you can imagine, such inconvenience can break a lot of proofs and computations. So, it is often assumed that $1\neq 0$ in a particular ring, literally.
On
I think the answers are clear. Here is one more just to be explicit. We are concerned with commutative rings with a multiplicative identity.
Suppose I have a set $S=\{a,b,c\}$ with commutative operations satisfying $a=a+c=b+b=ab$, $b=a+a=b+c=bb$ , $c=a+b=c+c=ac=bc=cc.$ Then one way or another you can check the rules for a ring and verify that the structure is a ring with additive identity $c$ and multiplicative identity $b$. A shorter way to say that is $0=c$ and $1=b$.
Without the rule you mention $T=\{x\}$ would count as a ring with $x+x=xx=x.$ Since $a+x=a$ for everything in the singleton set $T,$ $x=0$, similarly $ax=a$ gives $x=1.$
It turns out that $T$ is the only thing which follows all the ring rules except the requirement $0 \neq 1$. It is desireable to not have $T$ count as a ring. That uniqueness. Claim isnt that hard to prove but first you need some smaller results such as $0a=0$ . I do not recall for sure, but it might be cleanest to use $0\neq 1$ in an early proof.
In general when discussing rings we like to use $1$ as notation for the multiplicative identity and $0$ as notation for the additive identity because this is what we are used to for $\mathbb{R}$ or $\mathbb{Z}$, even though in other rings they won't literally be $1$ and $0$. In this case, the notation $1\neq 0$ is a quick way to say the the multiplicative and additive identities are not the same.