Wolfram MathWorld defines the Euler Totient function as follows:
The totient function phi(n), also called Euler's totient function, is defined
as the number of positive integers <=n that are relatively prime to (i.e., do
not contain any factor in common with) n, where 1 is counted as being
relatively prime to all numbers
By this definition would $\phi(0)=0$?
Yes, because we must conclude that there are zero positive integers less than or equal to zero. We do not even have to consider the remainder of the criteria or the fact that $1$ is relatively prime to all numbers.