Every linear map between finite dimensional vector spaces can be represented by a matrix, once bases are chosen for the domain and range spaces.
Question: What is the matrix representation for the linear space isomorphism \begin{align} \mathbb{R}^{2\times2}&\rightarrow\mathbb{R}^4\\ \begin{bmatrix}a&b\\c&d\end{bmatrix}&\mapsto[a\;b\;c\;d] \end{align} between $\mathbb{R}^4$ and the space $\mathbb{R}^{2\times2}$ of $2\times2$ matrices, given the standard bases of these spaces?
Edit: Let's say the standard basis of $\mathbb{R}^{2\times2}$ is: $$ \bigg\{\begin{bmatrix}1&0\\0&0\end{bmatrix},\begin{bmatrix}0&1\\0&0\end{bmatrix},\begin{bmatrix}0&0\\1&0\end{bmatrix},\begin{bmatrix}0&0\\0&1\end{bmatrix}\bigg\} $$
Given a map $V \to U$ with bases $\{e_i\}_{i=1}^{n}$ and $\{u_j\}_{i=1}^n$ respectively, a matrix form is given by forming columns $[u_1 \dots u_n]$ where $e_i \to a_{1i}u_1+ \dots a_{ni}u_n$.
In your case the map is $e_i \to u_i$, where $u_i$ is the standard basis for $\mathbb R^4$.
This means that the matrix representation is just the identity.