I have a feeling this question is a duplicate, but it's not coming up in "Questions that may already have your answer."
We all know very well that $F(0) = 0$, $F(1) = 1$ and $F(n) = F(n - 2) + F(n - 1)$ for all $n > 1$.
I'm wondering about $n < 0$. My first thought was $F(-n) = -F(n)$, which is appealing from a multiplicative point of view, as it seems to preserve certain identities, like $F(n)^2 = F(n - 1) F(n + 1) - (-1)^n$.
But it doesn't quite make sense from an additive point of view, it doesn't seem to work both "forwards" and "backwards." For example, it would give us $F(-1) + F(0) = -1 \neq F(1)$.
How do we extend $F(n)$ to negative $n$ so as to maintain both the related identities and the basic defining identity?

$ \def\zz{\mathbb{Z}} \def\matrix#1{\left[\begin{array}{c}#1\end{array}\right]} $The recurrence relation $F_{n+2} = F_{n+1}+F_n$ for every $n \in \zz$ uniquely defines the sequence in both directions once you fix $F_0 = 0$ and $F_1 = 1$. Note that $F_{-1} = 1$.
Take any $n \in \zz$.
Then $\matrix{F_{n+1}\\F_n} = \matrix{1&1\\1&0} \matrix{F_n\\F_{n-1}}$ by the recurrence.
Thus $\matrix{F_{n+1}&F_n\\F_n&F_{n-1}} = \matrix{1&1\\1&0} \matrix{F_n&F_{n-1}\\F_{n-1}&F_{n-2}} = \matrix{1&1\\1&0}^n \matrix{F_1&F_0\\F_0&F_{-1}} = \matrix{1&1\\1&0}^n$.
(Note that the above is valid even for negative $n$. We just need one induction for positive $n$ and one more for negative $n$, along with the fact that $\matrix{1&1\\1&0}$ is invertible.)
Thus $F_{n+1} F_{n-1} - {F_n}^2 = \det\matrix{F_{n+1}&F_n\\F_n&F_{n-1}} = (-1)^n$.
It holds for any $n \in \zz$, contrary to your assumption that it would break down!
If matrices are new to you, see this explanation of the motivation and intuition behind matrices.