Set $$ I_n :=\int_0^1\left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n \:\mathrm{d}x \qquad n=1,2,3,\cdots. $$
We have $$I_1 =\gamma, \quad I_2 =\log (2 \pi) - \frac 32, \quad I_3 = 6 \log A - \frac{31}{24}, \quad I_4 = 2 \log A + \frac{5 \zeta(3)}{2\pi^{2}}- \frac{49}{72}, \quad ...$$ where $A$ is the Glaisher-Kinkelin constant defined by $$ \begin{equation} \displaystyle A :=\lim_{n\to\infty}\frac{1^22^2\cdots n^n}{e^{-n^2/4}n^{\frac{n^2+n}{2}+\frac{1}{12}}}=1.28242712\cdots. \end{equation} $$
I wonder if there is a "simple" equivalent for $I_n$ as $n$ tends to $+\infty$?
Edit. I had designed the following integral $$\displaystyle \int_0^1\left(\frac{1}{\log x} + \frac{1}{1-x}\right)^2 \mathrm{d}x$$ which I submitted to American Mathematical Monthly (March 2012, problem 11629), the problem was then spread and came in this forum with different interesting solutions (I). An interesting general formula for $I_n$ has been found (II), but I don't think the latter formula is tractable for the above question on asymptotics.
The main idea is that, near the largest point of the integrand (which occurs at $x=0$), we have
$$ \frac{1}{\log x} + \frac{1}{1-x} \approx \frac{1}{\log x} + 1. $$
So we split the integral up as
$$ \int_0^1 \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx = \left[\int_0^{1/e} + \int_{1/e}^1 \right] \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx. $$
For the second integral we have the bound
$$ 0 < \int_{1/e}^{1} \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx < (e-1)^{-n} $$
and for the first integral we write
$$ \begin{align} \int_0^{1/e} \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx &= \int_0^{1/e} \exp\left\{n \log\left(\frac{1}{\log x} + \frac{1}{1-x}\right)\right\}dx \\ &= \int_0^{1/e} \exp\left\{n \log\left(\frac{1}{\log x} + 1\right) + n f(x)\right\}dx, \end{align} $$
where
$$ f(x) = \log\left(1+\frac{x}{\left(\frac{1}{\log x}+1\right)(1-x)}\right) = O(x) \quad \text{as $x \to 0$.} $$
We therefore expect that the largest contribution comes from a neighborhood of radius $1/n$ of the point $x=0$. The rest of the integral is bounded by
$$ 0 < \int_{1/n}^{1/e} \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx < \left(-\frac{1}{\log n} + \frac{n}{n-1}\right)^n = O(e^{-n/\log n}). $$
For $0 \leq x \leq 1/n$ we have
$$ \exp\{nf(x)\} = 1 + O(nx), $$
so, after combining our estimates, we arrive at
$$ \begin{align} \int_0^1 \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx &= \int_0^{1/n} \exp\left\{n \log\left(\frac{1}{\log x} + 1\right)\right\}dx \\ &\qquad + O\left(n \int_0^{1/n} x \exp\left\{n \log\left(\frac{1}{\log x} + 1\right)\right\}dx\right)\\ &\qquad + O(e^{-n/\log n}). \end{align} $$
Now we make the change of variables $-y = \log\left(\frac{1}{\log x} + 1\right)$, transforming our integrals into
$$ \begin{align} &\int_0^{1/n} \exp\left\{n \log\left(\frac{1}{\log x} + 1\right)\right\}dx \\ &\qquad = \int_0^{-\log(1-1/\log n)} e^{-ny} \exp\left\{\frac{1}{e^{-y}-1}\right\} \frac{e^{-y}}{(1-e^{-y})^2}\,dy \end{align} $$
and
$$ \begin{align} &\int_0^{1/n} x\exp\left\{n \log\left(\frac{1}{\log x} + 1\right)\right\}dx \\ &\qquad = \int_0^{-\log(1-1/\log n)} e^{-ny} \exp\left\{\frac{2}{e^{-y}-1}\right\} \frac{e^{-y}}{(1-e^{-y})^2}\,dy. \end{align} $$
We can expand the factor which is independent of $n$ as
$$ \begin{align} \exp\left\{\frac{1}{e^{-y}-1}\right\} \frac{e^{-y}}{(1-e^{-y})^2} &= \exp\left\{-\frac{1}{y}-\frac{1}{2}\right\} \sum_{j=-2}^{\infty} c_j y^j \\ &= \exp\left\{-\frac{1}{y}-\frac{1}{2}\right\} \left( \frac{1}{y^2} -\frac{1}{12 y} - \frac{23}{288} + \frac{427 y}{51840} + \cdots \right), \end{align} $$
so on truncating the expansion at $j=J-1$ we obtain
$$ \begin{align} \int_0^1 \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx &= \sum_{j=-2}^{J-1} \frac{c_j}{\sqrt{e}} \int_0^{-\log(1-1/\log n)} e^{-ny} e^{-1/y} y^j \,dy \\ &\qquad + O\left(\int_0^{-\log(1-1/\log n)} e^{-ny} e^{-1/y} y^J \,dy\right) \\ &\qquad + O\left(n \int_0^{-\log(1-1/\log n)} e^{-ny} e^{-2/y} y^{-2} \,dy \right) \\ &\qquad + O(e^{-n/\log n}). \end{align} $$
All that remains is to reattach the tails of the integrals. By doing so we add an error of no more than
$$ \begin{align} &\int_{-\log(1-1/\log n)}^\infty e^{-ny} e^{-1/y} y^j \,dy \\ &\qquad = \int_{-\log(1-1/\log n)}^\infty e^{-ny/2} \left(e^{-ny/2} e^{-1/y} y^j\right) \,dy \\ &\qquad \leq \sqrt{\int_{-\log(1-1/\log n)}^\infty e^{-ny}\,dy} \cdot \sqrt{\int_{-\log(1-1/\log n)}^\infty e^{-ny} e^{-2/y} y^{2j}\,dy} \\ &\qquad = \sqrt{\frac{2}{n}} \left(1-\frac{1}{\log n}\right)^{n/2} \sqrt{\int_{-\log(1-1/\log n)}^\infty e^{-ny} e^{-2/y} y^{2j}\,dy} \\ &\qquad < \sqrt{\frac{2}{n}} \left(1-\frac{1}{\log n}\right)^{n/2} \sqrt{\int_{0}^\infty e^{-ey} e^{-2/y} y^{2j}\,dy} \\ &\qquad = O\left(n^{-1/2} e^{-n/(2\log n)}\right) \end{align} $$
for $n > e$ by the Cauchy-Schwarz inequality, with the same bound when $e^{-1/y}$ is replaced with $e^{-2/y}$. Thus we have
$$ \begin{align} \int_0^1 \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx &= \sum_{j=-2}^{J-1} \frac{c_j}{\sqrt{e}} \int_0^\infty e^{-ny} e^{-1/y} y^j \,dy \\ &\qquad + O\left(\int_0^\infty e^{-ny} e^{-1/y} y^J \,dy\right) \\ &\qquad + O\left(n \int_0^\infty e^{-ny} e^{-2/y} y^{-2} \,dy \right) \\ &\qquad + O\left(n^{-1/2} e^{-n/(2 \log n)}\right). \end{align} $$
To normalize these integrals a little bit we can substitute $y = u/\sqrt{n}$ to get
$$ \begin{align} \int_0^1 \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx &= \sum_{j=-2}^{J-1} \frac{c_j}{\sqrt{e}} n^{-(j+1)/2} \int_0^\infty e^{-\sqrt{n}(u+1/u)} u^j \,du \\ &\qquad + O\left(n^{-(J+1)/2} \int_0^\infty e^{-\sqrt{n}(u+1/u)} u^J \,du\right) \\ &\qquad + O\left(n^{3/2} \int_0^\infty e^{-\sqrt{n}(u+2/u)} u^{-2} \,du \right) \\ &\qquad + O\left(n^{-1/2} e^{-n/(2 \log n)}\right). \end{align} $$
With the basic Laplace method estimate
$$ \int_0^\infty e^{-\sqrt{n}(u+\alpha/u)} u^j \,du \sim \alpha^{1/4} \sqrt{\frac{\pi}{n}} e^{-2\sqrt{\alpha n}} $$
we may conclude that the series we've written is actually an asymptotic series, i.e.
$$ \int_0^1 \left(\frac{1}{\log x} + \frac{1}{1-x}\right)^n\,dx \sim \sum_{j=-2}^{\infty} \frac{c_j}{\sqrt{e}} n^{-(j+1)/2} \int_0^\infty e^{-\sqrt{n}(u+1/u)} u^j \,du. $$
Here we recognize that
$$ \int_0^\infty e^{-\sqrt{n}(u+1/u)} u^j \,du = 2 K_{-j-1}\left(2\sqrt{n}\right), $$
where $K_\nu$ is the modified Bessel function of the second kind (see eq. 10.32.10, DLMF).
We can transform this asymptotic series into one in terms of elementary functions by using the known asymptotic expansion for $K_\nu(r)$ as $r \to \infty$ (DLMF reference). In our case we have
$$ K_{-j-1}\left(2\sqrt{n}\right) \sim \frac{\sqrt{\pi}}{2} n^{-1/4} e^{-2\sqrt{n}} \sum_{k=0}^{\infty} \frac{a_k(j+1)}{2^k} n^{-k/2}, $$
where $a_0(j+1) = 1$ and
$$ a_k(j+1) = \frac{1}{k!8^k}\prod_{m=1}^{k} \left(4(j+1)^2-(2m-1)^2\right). $$
Substituting this into our asymptotic expansion yields
$$ \begin{align} \frac{2}{\sqrt{e}}\sum_{j=-2}^{\infty} c_j n^{-(j+1)/2} K_{-j-1}\left(2\sqrt{n}\right) &= \sqrt{\frac{\pi}{e}} n^{-1/4} e^{-2\sqrt{n}} \sum_{j=-2}^{\infty} \sum_{k=0}^{\infty} \frac{c_j a_k(j+1)}{2^k} n^{-(j+k+1)/2} \\ &= \sqrt{\frac{\pi}{e}} n^{1/4} e^{-2\sqrt{n}} \sum_{\ell = 0}^{\infty} \left(\sum_{j+k+2=\ell} \frac{c_j a_k(j+1)}{2^k}\right)n^{-\ell/2}, \end{align} $$
So we conclude that