When is it true that $\nexists g\ne e$ such that $\phi(g)=e$ for a group homomorphism $\phi: G\mapsto H$ and $|H|\not\mid|G|$?

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I was thinking if it is possible to have $g\ne e$ such that $\phi(g)=e$ for a group homomorphism $\phi: G\mapsto H$

It's not always true because $\phi(2)=0$ when $G=\Bbb Z_4$ and $H=\Bbb Z_2$

So what if $|H|\not\mid|G|$?

We have that $o(\phi(g))$ divides $o(g)$ and $|H|$ because $\phi(\langle g\rangle)$ is a subgroup of $H$

If we had $(|H|,\phi(\langle g\rangle))=1$ then we would have $o(\phi(g))=1$ and so $\phi(g)=e$

What other necessary/sufficient constraints are there for the existance of $g\in G\backslash\{e\}$ with $\phi(g)=e$?

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First of all, let's use a fact to make your question a bit neater.

The following conditions are equivalent:

  • $\phi : G \to H$ is injective (one-to-one)
  • $\ker \phi = \{e\}$
  • There does not exist an element $g \in G$ with $g \neq e$ such that $\phi(g) = e$

With this in mind, I believe that you are asking this: under what conditions does there exist an injective homomorphism from $G$ to $H$? The answer to this question is that such a homomorphism will exist if and only if $H$ contains a subgroup isomorphic to $G$. For the example of $G = \Bbb Z_2$ and $H = \Bbb Z_4$, we see that the map $\phi([n]_2) = [2n]_4$ is injective, and $\Bbb Z_4$ contains the subgroup $\{[0]_4,[2]_4\}$ which is isomorphic to $\Bbb Z_2$.

One way to prove this is to use the first isomorphism theorem. In particular, we know that for any homomorphism, $\phi(G) \cong G/\ker\phi$. However, if $\ker \phi = \{e\}$, then we have $G/\ker \phi \cong G$. So, if $\phi$ is an injective homomorphism, then $\phi(G) \cong G$, and $\phi(G)$ (the image of $\phi$) is a subgroup of $H$.

Conversely, suppose that $H$ has a subgroup $K \subset H$ and that $K \cong G$. Then, an isomorphism $\phi:G \to K$ means that we have the injective homomorphism $i_K \circ \phi:G \to H$, where $i_K:K \to H$ is the inclusion map.