When is the $B$ defined through $\forall i:a_i=v_i\times B$ existent and unique?

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Of course the motivation is to understand what data is needed to define the (electric and) magnetic field through the lorentz force. So suppose we are given $a_1,\ldots,a_n,v_1,\ldots,v_n\in\mathbb R^3$ and we want to verify the existence and uniqueness of a $B\in\mathbb R^3$ such that $\forall i:a_i=v_i\times B$. If I had to make a guess, then I would say that $B$ exists and is unique if $n=3$ and $v_1,v_2,v_3$ is a basis, but I don't know how to prove this. Any help is much appreciated :)

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Uniqueness holds for $n>2$, provided the $v_i$ are distinct and non-zero. Existence is not guaranteed for any $n$ without conditions on the $F_i$ and $v_i$. Namely, if there is such a $B$, then we need $v_i\times F_j+v_j\times F_i=0$*. In fact, this condition will give existence.

*I have just realised I made a mistake. The conditions should be $v_i\cdot F_j+v_j\cdot F_i=0$.

The span of the $v_i$ doesn't need to be 3-dimensional: in fact for $n=2$, there is a unique solution provided the conditions hold. We can choose a basis in which $v_1=(1,0,0)^t$, $v_2=(0,1,0)^t$. Then the conditions $v_i\cdot F_j+v_j\cdot F_i=0$ mean that the two forces take the form $F_1=(0,a,b)^t$, $F_2=(-a,0,c)^t$. Then the equations $F_i=v_i\times B$ read

$$ \begin{pmatrix} 0\\ a\\ b \end{pmatrix} = \begin{pmatrix} 1\\ 0\\ 0 \end{pmatrix} \times \begin{pmatrix} B_1\\ B_2\\ B_3 \end{pmatrix} = \begin{pmatrix} 0\\ -B_3\\ B_2 \end{pmatrix} $$ and $$ \begin{pmatrix} -a\\ 0\\ c \end{pmatrix} = \begin{pmatrix} 0\\ 1\\ 0 \end{pmatrix} \times \begin{pmatrix} B_1\\ B_2\\ B_3 \end{pmatrix} = \begin{pmatrix} B_3\\ 0\\ -B_1 \end{pmatrix} $$

So, we get the unique solution $B=(-c,b,-a)^t$.