Let us say that a vector space $V$ is an algebraic dual space if there exist a vector space $U$ such that $V$ is isomorphic to $U^*$, the vector space of all linear maps from $U$ to the corresponding field of scalars.
It is known that if $V$ is finite-dimensional then $V$ and $V^*$ are isomorphic, hence $V$ is an algebraic dual space. On the other side, it is also known that the dimension of an algebraic dual space cannot be countably infinite, hence not all vector spaces are algebraic dual spaces.
Question: Is there any characterization of vector spaces that are algebraic dual spaces?
I am mostly interested in the case of vector spaces over reals.
Let $F$ be a field, $\kappa$ be a cardinal. Denote $F^\kappa$ the vector space of all functions $f\colon\kappa\to F$.
Let $V$ be a vector space over $F$. We shall use the following facts.
For a proof of the first statement, see here. The second one follows from the fact that every element of $V$ can be uniquely represented by a finite linear combination of the elements of a basis of $V$. For the third statement, notice that every map from a basis of $V$ to $F$ can be uniquely extended to a linear map from $V$ to $F$. The last statement follows from the previous two.
Claim. Let $V$ be a vector space over a field $F$. Then $V$ is an algebraic dual space if and only if $\mathrm{dim}\ V<\omega$ or $\mathrm{dim}\ V=\left|F\right|^\kappa$ for some infinite cardinal $\kappa$.
Proof. Assume that $V=U^*$ and $\mathrm{dim}\ V\ge\omega$. Then $V$ is isomorphic to $F^\kappa$ where $\kappa=\mathrm{dim}\ U$. We have $\kappa\ge\omega$ since otherwise $V$ would be isomorphic to $U$ and thus $\mathrm{dim}\ V$ would be finite. By 1, $\dim V=\left|F\right|^\kappa$. This finishes one direction.
For the other direction, assume that $\dim V=\left|F\right|^\kappa$ for some $\kappa\ge\omega$. Then, by 1, $\dim V=\dim F^\kappa$, hence, by 2, $V$ and $F^\kappa$ are isomorphic, and, by 3, $V$ is an algebraic dual space. To complete the proof, notice that 4 implies that if $\dim V$ is finite then $V$ is an algebraic dual space. q.e.d.