Where I got my Info <- May want to fact check me
So given that deciding whether a graph with N vertices is colorable with K colors is NP-Complete, and focusing on the case where this can be determined in polynomial time, and knowing upper and lower bounds of χ(G) being, not including much optimizations, an integer from 1 to K (Can be derived from Brook's Theorem + you can't have half a color).
Don't we already have methods of finding a integer between 1 to K in $\lceil\log_{2}\left(K\right)\rceil$ guesses? Meaning that if deciding a graph can be done in polynomial time ( $O\left(K^{c}\right)$ ), then couldn't the $O$ of χ(G) be $\lceil\log_{2}\left(K\right)\rceil*O\left(K^{c}\right)$, simplifying to $O\left(K^{c}\right)$, meaning that χ(G) is NP-Complete?
EDIT: Actually, so can't we confirm it in polynomial time too just by showing that showing that for A, where A is the chromatic number, and show that A-1 colors can't color the graph & A colors can color the graph in NP-Complete time (because it's just the Deciding stuff above), then if P = NP then we can check this in polynomial time? Along with the case of P $\neq$ NP, then χ(G) is NP-Complete?
While this isn't confirming it's the answer in polynomial time exactly, if P vs Np is true, then it would be polynomial time, else it's not polynomial
---So if P=NP, then χ(G) is NP-Complete which along with the previous statement, makes χ(G) is P. If P /= NP, then χ(G) is NP-Hard, meaning that χ(G) is NP. This just seems like a double layered NP-Complete now.
I apologize for any overlooks I may have taken, this is just a thought I had and needed to get out. EDIT- Ok that may have been confusing.
A $\mathcal{NP}$-complete problem is by definition a decision problem (the answer is true of false). For example, given $k$, deciding if a graph is $k$-colorable is $\mathcal{NP}$-complete.
An optimization problem, like computing $\chi(G)$ can't be $\mathcal{NP}$-complete, because this expected answer is a number, not true/false.
However, you are right that we can query $\chi(G)$ with a polynomial number of oracles to the $k$-coloring problem, but it does not make $\chi(G)$ $\mathcal{NP}$-complete. This result is more general. For a given optimization problem, if its decision problem is $NP$-complete and that the objective function is computable in polynomial time, you can solve it in polynomial time using a polynomial number of oracle to the decision problem with binary search.