If the rationals are dense in the rationals, meaning there is a rational between every 2 irrationals, then there is essentially a rational number for every irrational.
If there is aleph irrationals, why isnt there aleph rationals if there exists a unique rational for every irrational number?
Perhaps, but this neglects that we only posit the existence of one rational, and certainly nothing about uniqueness. For instance, between $-\sqrt 2$ and $\sqrt 2$ you have the rational $0$. And between $-\sqrt 5$ and $\sqrt 5$ as well. Or between $-x$ and $x$, for any positive irrational $x$. (In fact, the density of $\mathbb{Q}$ ensures that there are infinitely many rationals between any two reals, and the irrationals satisfy this too, making matters a fair bit more complicated.)
This is certainly not enough to argue anything about cardinality.
Moreover, if the irrationals $\mathbb{R} \setminus \mathbb{Q}$ are indeed countable, then $$ \mathbb{R} = \mathbb{Q} \cup (\mathbb{R} \setminus \mathbb{Q}) $$ giving the reals as a finite union of disjoint countable sets, hence being countable. However, it is easy to prove that $\mathbb{R}$ is uncountable and $\mathbb{Q}$ is countable, so that means that $\mathbb{R} \setminus \mathbb{Q}$ must be uncountable.