A representation of a Lie group $G$ on a vector space $V$ is defined to be a Lie group homomorphism $\rho$ such that $$\rho: G \rightarrow GL(V),$$ whereas the representation of a Lie algebra $\mathfrak{g}$ on a vector space $V$ is defined to be a Lie algebra homomorphism $\phi$ such that $$\phi: \mathfrak{g} \rightarrow \text{End}(\phi).$$
Why is the image space for a Lie algebra representation less restricted than for a Lie group (requiring only a homomorphism instead of an isomorphism)?
The short answer: Because $GL(V)$ is a group and $\mathrm{End}(V)$ is a Lie algebra.
In particular, $GL(V)$ has the following:
Whereas $\mathrm{End}(V)$ has the following:
So it is only natural to represent a Lie group in the group $GL(V)$, and a Lie algebra in the algebra $\mathrm{End}(V)$.