Why is $U(10)\not\approx U(12)$?

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I'm trying to understand this example on isomorphism but failing to do so. I know that if two groups have a differing number of elements of each order they are not isomorphic. I assume this is what they are saying. Particularly, how is it that $\phi(3)\phi(3)$ and $\phi(1)\phi(1)$ both equal 1?

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$$\begin{align*} U(10)&=\{x\in\mathbb{Z}/10\mathbb{Z}:x\text{ is a unit}\}=\{1+10\mathbb{Z},\;3+10\mathbb{Z},\;7+10\mathbb{Z},\;9+10\mathbb{Z}\}\\ U(12)&=\{x\in\mathbb{Z}/12\mathbb{Z}:x\text{ is a unit}\}=\{1+12\mathbb{Z},\;5+12\mathbb{Z},\;7+12\mathbb{Z},\;11+12\mathbb{Z}\}\\ \end{align*}$$ Both $U(10)$ and $U(12)$ are groups with $4$ elements.

(For convenience, we often drop the coset notation, but remember that it's still there implicitly.)

As is explained in the excerpt, we have $x^2=1$ for every $x\in U(12)$. That is, $$\left.\begin{align*} (1+12\mathbb{Z})^2&=1+12\mathbb{Z}\\ (5+12\mathbb{Z})^2&=25+12\mathbb{Z}\\ (7+12\mathbb{Z})^2&=49+12\mathbb{Z}\\ (11+12\mathbb{Z})^2&=121+12\mathbb{Z} \end{align*}\right\}\text{ all equal }1+12\mathbb{Z}$$ (In other words, $25\equiv 1\bmod 12$, and $49\equiv 1\bmod 12$, and $121\equiv 1\bmod 12$.)

We suppose, for the sake of contradiction, that $\phi:U(10)\to U(12)$ is a function that is a group isomorphism. In particular, for any input $a\in U(10)$, the output $\phi(a)$ is an element of $U(12)$, and (as observed) therefore must have the property that $\phi(a)^2=1$.

But since $$\begin{align*} \phi(9+10\mathbb{Z})=\phi\biggl((3+10\mathbb{Z})^2\biggr)=\phi(3+10\mathbb{Z})^2=1+12\mathbb{Z}\\ \phi(1+10\mathbb{Z})=\phi\biggl((1+10\mathbb{Z})^2\biggr)=\phi(1+10\mathbb{Z})^2=1+12\mathbb{Z}\\ \end{align*}$$ (No matter what the value of $\phi(3+10\mathbb{Z})$ is! all we need to know is that it's an element of $U(12)$!) we see that $\phi$ is not injective, and therefore cannot be a group isomorphism as was assumed.

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As written explicitly, in $U(12)$ we have $g^2=1$ for every element $g$. Hence, $\phi(3)^2=\phi(1)^2=1$.

However, what you wrote about differing numbers of elements of the same order is indeed a simpler way to think of it. In $U(10)$ there are elements of order $4$, and in $U(12)$ there are no such elements. Consequently, the two groups cannot be isomorphic to one another.