This is basic algebraic geometry, there's a question at the end but please check that my reasoning all the way up to the question also holds:
Given a grassmannian $Gr(k,V)$, we can embed it to the projectiviation of a wedge space, by the map:
$$\iota : Gr(k,V) \to \mathbb{P}(\wedge^k V) \\ W \mapsto [w] $$
In the case that $k=3$ and dim $ V = 5$, we can compute the maximal $3 \times 3$ minors of the matrix consisting of the vectors spanning $W$, there are ${5\choose3} = 10$ such minors and that will provide homogeneous coordinates $w = [Z_0...Z_9] \in \mathbb{P}(\wedge^3 K^5) \sim \mathbb{P}^9$.
For the life of me, I can't figure out why this isn't surjective. Can someone give me an example of a $p \in \mathbb{P}^9 $ that isn't hit by any subspace $W \in Gr(3, K^5)$ and explain why it is so?
But $G(3,5)$ has dimension $3(5-3)=6$, which is far less than $9$.
The key idea you're missing is that the image of the Plücker map consists of all (projectivized) decomposable $k$-vectors, which is in general a very thin subset of $\Bbb P(\Lambda^k V)$.