I know that variance is the square of the standard deviation.
I must to answer if is true or false this statement:
If the variance is equal to standard deviation, then they are just both equal to 1.
I answered true, because if standard deviation is $1$ , its square is $1^2$, that is the same.
But the correct answer was false, so I would like to know why it is false
Unfortunately, you've fallen into the pit of concluding that $P \implies Q$ is the same as $Q \implies P$. The converse is not equivalent to the original statement.
Yes, it's true that if the variance is $1$ then the standard deviation equals the variance.
No, it's not true that variance being equal to standard deviation implies that the variance is $1$; after all, as pointed out in the comments, $x^2 = x$ has two solutions.