Given the coupled wave equations:
$$ \frac{\partial }{\partial t} [u~~v] + \begin{pmatrix} a & c \\ c & a \end{pmatrix} \frac{\partial }{\partial x} [u~~v] = [0~~0]. $$
I want to transform this problem into a decoupled system with variables [r,s]. Can someone give me an idea on where to start?
One place to start is to choose a basis in which $\begin{bmatrix} a & c \\ c & a \end{bmatrix}$ is diagonal. So we diagonalize by finding eigenvalues and eigenvectors. The characteristic polynomial is $\lambda^2-2a\lambda+a^2-c^2$ which has roots $\frac{2a \pm (4a^2 - 4a^2+4c^2)^{1/2}}{2} = a \pm c$. The eigenvectors then satisfy
$$-cx_1+cx_2=0 \Rightarrow x_1=x_2 \\ cy_1+cy_2=0 \Rightarrow y_1=-y_2.$$
So you can choose the basis $\begin{bmatrix} 1 \\ 1 \end{bmatrix}$ and $\begin{bmatrix} 1 \\ -1 \end{bmatrix}$, i.e. $r=u+v$ and $s=u-v$. This change of variables will make the matrix diagonal, which will decouple that part of the system.
Now you want to write
$$\begin{bmatrix} u \\ v \end{bmatrix} = \begin{bmatrix} 1 & 1 \\ 1 & -1 \end{bmatrix}^{-1} \begin{bmatrix} r \\ s \end{bmatrix} = \frac{1}{2} \begin{bmatrix} 1 & 1 \\ 1 & -1 \end{bmatrix} \begin{bmatrix} r \\ s \end{bmatrix}$$
and plug that into your original equation to see how the full equation decouples.