The canonical example that a non-null polynomial might be identically zero is to take $x^2 - x$ over a field of characteristic 2.
I wonder if this feature is exclusive to characteristic 2, i.e., is it true that if char$F \neq 2$ then the only identically zero polynomial is the null polynomial?
Thanks in advance.
As long as a field is finite, say $F=\{x_1,\dots,x_n\}$, you can use the polynomial $$P(X) = (X-x_1)(X-x_2)\dots (X-x_n).$$
It is easy to see that each $x_i$ is a root of $P$, so as a function it is zero on $F$, but it has degree $n$.