We wish to show that $[0, 1]\setminus \mathbb Q$ can't be exhausted by Jordan sets. What I mean by this is that there's no nested sequence of Jordan sets $J_1 \subseteq J_2 \subseteq \dots$ such that $\bigcup_{k=1}^{\infty}J_k = [0,1]\setminus\mathbb Q$
Jordan in this sense means Jordan Measurable (boundary is negligible)
Sadly, the fact that the boundary of the union is a subset of the union of the boundaries is only true for finite union, else this would be piece of cake.
How would you tackle this? It may be related to improper integration
Better answer than the above one as I don't invoke measures.
Notice that $X = [0,1]\setminus \mathbb Q$ doesn't have any interior points, $\text{int}(X) = \emptyset$, so if $J \subset X$ then also $\text{int}(J) = \emptyset$.
This means that $J \subseteq \partial J$. Now, if $J$ is Jordan measurable, then by definition $\partial J$ is negligible, so $J$ is negligible.
Thus if $X = \bigcup_{k=1}^{\infty}J_k$ then it follows that $X$ is negligible, since it's a countable union of negligible sets, and this is a contradiction, since $X$ is not negligible.