Let $v$,$w$ be two complex vectors in $C^3$ satisfying that $v^tv=w^tw=0$ and $v$,$w$ are linearly independent.
I want to know whether there always exists a 3×3 complex orthogonal matrix $g≠I_3,-I_3$ $g^tg=I_3$ such that both $v$ and $w$ are eigenvector of $g$?
Yes,under the conditions stated, $$ g=I_3-\frac{2}{w^tv}\big(wv^t+vw^t\big) $$ is such an "orthogonal" matrix. The stated conditions guarantee that $\ w^tv\ne0\ $. \begin{align} gv&=v-\frac{2}{w^tv}\big(v^tvw+w^tvv\big)\\ &=-v\ ,\ \text{ and}\\ gw&=w-\frac{2}{w^tv}\big(v^tww+w^twv\big)\\ &=-w\ , \end{align} so $\ v\ $ and $\ w\ $ are eigenvectors of $\ g\ $ corresponding to the eigenvalue $\ {-}1\ $.
Also, $\ g\ $ is symmetric, so \begin{align} g^tg&=g^2\\ &=I_3^2-\frac{4}{w^tv}\big(wv^t+vw^t\big)+\frac{4}{\big(w^tv\big)^2}\big(wv^t+vw^t\big)^2\\ &=I_3-\frac{4}{w^tv}\big(wv^t+vw^t\big)+\frac{4}{\big(w^tv\big)^2}\big(v^twwv^t+w^tvvw^t\big)\\ &=I_3-\frac{4}{w^tv}\big(wv^t+vw^t\big)+\frac{4w^tv}{\big(w^tv\big)^2}\big(wv^t+vw^t\big)\\ &=I_3\ . \end{align}