In the usual definition of the field $\mathbb{C}$, as $\{(a,b):a,b\in\mathbb{R}\}$, the field $\mathbb{R}$ is not exactly a subset of $\mathbb{C}$, but only an isomorphic copy of the subfield $\{(a,0):a\in\mathbb{R}\}$. I am wondering: can we define $\mathbb{C}$ as the set $$ \mathbb{C}=\mathbb{R}\cup\{(a,b):a,b\in\mathbb{R}\ \text{and}\ b\neq0\}\ ? $$ In this case, how to define the operations?
$\mathbf{Remark}$: We know that the operations of $\{(a,0)\}$ can be extend to $\{(a,b)\}$. Since $\mathbb{R}≅\{(a,0)\}$, can we prove that the operations of $\mathbb{R}$ can be extend to $\mathbb{R}∪\{(a,b):b≠0\}$?
You can do it without any difficulty. Consider the map $$ f\colon\mathbb{R}\cup\underbrace{\{(a,b):a,b\in\mathbb{R},b\ne0\}}_{X} \to\mathbb{R}\times\mathbb{R} $$ defined in the obvious way: $$ f\colon a\in\mathbb{R}\mapsto(a,0), \qquad f\colon (a,b)\in X\mapsto(a,b), $$ and define the operations on $\mathbb{R}\cup X$ by $$ u+v=f^{-1}(f(u)+f(v)), \qquad uv=f^{-1}(f(u)f(v)) $$
However, it is dubious if you gain something with respect to identifying $a$ with $(a,0)$ and setting $i=(0,1)$, so $$ (a,b)=(a,0)+(b,0)(0,1)=a+bi $$