I would appreciate help/hints solving the following exercise from Humphreys book "Reflection Groups and Coxeter Groups", page 11, exercise 1.
Let $\Phi$ be a root system of rank $n$ of unit vectors in $V$ and let $\Psi\subset\Phi$ be a subset of size $n$. If the mutual angles in $\Psi$ agree with those between the roots of some simple system, then $\Psi$ is a simple root system.
Adding my own answer using a proposition which appears later in the book. This leaves me curious whether there is a solution using only the material appearing prior to the exercise.
Denote by $\Delta=\{\alpha_1,\dots,\alpha_n\}\subset\Phi$ the simple system with the same angles as $\Psi=\{\psi_1,\dots,\psi_n\}$. $\Phi$ is also normalized so $(\psi_i,\psi_j)=(\alpha_i,\alpha_j)$ for every $1\leq i,j \leq n$. Denote by $W$ the reflection group generated by the reflections $S_\beta$ such that $\beta\in\Phi$.
We need to show that $\Psi$ is a simple root system ($|\Psi|=n$ therefore it is enough to show that $\Psi$ is linearly independent and that every $\beta\in\Phi$ is a linear combination of $\Psi$ in which all the coefficients have the same sign).
First show that $\Psi$ is linearly independent; assume the contrary, so there is some linear combination $ \sum_{i=1}^n c_i\psi_i = 0$ where not all $c_i$ are equal to zero. Therefore
$$ 0= (\sum_{i=1}^n c_i\psi_i,\sum_{i=1}^n c_i\psi_i) = \sum_{i=1}^n\sum_{j=1}^n c_i c_j(\psi_i,\psi_j) = \sum_{i=1}^n\sum_{j=1}^n c_i c_j(\alpha_i,\alpha_j) = (\sum_{i=1}^n c_i\alpha_i,\sum_{i=1}^n c_i\alpha_i). $$
Thus $\sum_{i=1}^n c_i\alpha_i=0$ where not all $c_i$ are equal to zero, in contradiction to $\Delta$ being linearly independent.
To show that every $\beta\in\Phi$ is a linear combination of $\Psi$ in which all the coefficients have the same sign, we will need the following proposition on page $24$ section $1.14$ of the same book where Humphreys shows that all the reflections in $W$ are of the form $S_\beta$ such that $\beta\in\Phi$. That is $$(*) \; S_\beta\in W \Leftrightarrow \beta\in\Phi $$
Let $T$ be the orthogonal transformation defined by $T(\alpha_i)=\psi_i$ (if $\Phi$ does not span $V$ entirely, then complete $\Delta$ to be a base of $V$ and define that $T$ fixed point wise the additional elements).
Let $\beta$ be a root in $\Phi$ and $\beta=\sum c_i\psi_i$. Applying $T^{-1}$ to both side of the equation we get $T^{-1}(\beta)=\sum c_i T^{-1}(\psi_i)=\sum c_i \alpha_i$. This is a linear combination of $\Delta$, thus proving that $T(\Phi)=\Phi$ shows that all $c_i$ have the same sign completing the proof.
Following $(*)$, it is enough to show that the reflection $S_{T(\beta)}\in W$ in order to show that $T(\beta)\in\Phi$. The following completes the proof (recall that simple reflections generate $W$, thus $S_\beta$ is equal to a composition of some $k$ simple reflection $S_{\alpha_1}\cdots S_{\alpha_k}$): $$ S_{T(\beta)} = TS_\beta T^{-1} = TS_{\alpha_1}\cdots S_{\alpha_k} T^{-1} = TS_{\alpha_1}T^{-1}\cdot TS_{\alpha_2}T^{-1}\cdots TS_{\alpha_k} T^{-1} = S_{T(\alpha_1)}\cdots S_{T(\alpha_k)} = S_{\psi_1}\cdots S_{\psi_k} \in W.$$