About members of a basis of an inner product space

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Say we have an inner product space $V$ with a basis $\mathbb B=\{v_1,...,v_n\}$, can we say that for each $i,j\in[1,n],i\neq j$ we have $\langle v_i,v_j \rangle=0$ because it's an inner product space?

$\langle x,y\rangle$ is the inner product.

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No, not all bases are orthogonal.

Take $V=\mathbb R^2$ and $v_1=(1,0)$ and $v_2=(1,1)$. Then $\{ v_1, v_2 \}$ is a basis but $\langle v_1, v_2 \rangle = 1 \ne 0$.

One thing that you can say about a generic basis is that its Gramian is not zero: $$ \begin{vmatrix} \langle v_1,v_1\rangle & \langle v_1,v_2\rangle &\dots & \langle v_1,v_n\rangle\\ \langle v_2,v_1\rangle & \langle v_2,v_2\rangle &\dots & \langle v_2,v_n\rangle\\ \vdots&\vdots&\ddots&\vdots\\ \langle v_n,v_1\rangle & \langle v_n,v_2\rangle &\dots & \langle v_n,v_n\rangle\end{vmatrix} \ne 0 $$