It is a classical exercise to prove that $e^\pi>\pi^e$. But... is there a way to prove $\sin(e^\pi)<\sin(\pi^e)$ without calculator?
I was trying to prove that $13\pi/2<\pi^e$ and $e^\pi<15\pi/2$ and use monotone decreasing property of $\sin$ in $[13\pi/2,15\pi/3]$, but i couldn't prove the last inequalities.
First, let us prove that $\frac{13\pi}{2}<\pi^e$.
We know that $$e>\frac{19}{7}$$
because the integral
$$\frac{1}{14}\int_0^1 x^2(1-x)^2e^xdx = e-\frac{19}{7}$$
has positive integrand.
Let us use $$\frac{25}{8}<\pi<\frac{22}{7}$$
to transform the inequality
$$\frac{13\pi}{2}<\pi^e$$
into a stricter one with integers only
$$\frac{13}{2}\frac{22}{7}=\frac{143}{7}<\left(\frac{25}{8}\right)^\frac{19}{7}$$
This transforms into $$143^7·8^{19} < 25^{19}·7^7$$ or the lengthy $$176222766583426849287556934139904 < 299603198072873055934906005859375$$
which proves $\frac{13\pi}{2}<\pi^e$.
For $e^\pi<\frac{15\pi}{2}$
Let us apply logarithms to both sides, to obtain the equivalent inequality
$$\pi < \log\frac{15\pi}{2}$$
Now use the inequality $$\frac{25}{8}<\pi < \frac{22}{7}$$
to write the stricter inequality
$$\frac{22}{7} < \log{\frac{3·5^3}{2^4}} = \log(3)+3\log(5)-4\log(2)$$
Now we need lower bounds for $\log(3)$ and $\log(5)$ and an upper bound for $\log(2)$, because of the different signs involved.
Consider the following ternary BBP-type series for $\log(3)$ and $\log(5)$ $$\log(3)=\sum_{k=0}^\infty \frac{1}{9^{k+1}}\left(\frac{9}{2k+1}+\frac{1}{2k+2}\right)$$
$$\log(5)=\frac{4}{27}\sum_{k=0}^\infty \frac{1}{81^k}\left(\frac{9}{4k+1}+\frac{3}{4k+2}+\frac{1}{4k+3}\right)$$
Taking the first two terms yields inequalities
$$log(3)>\frac{355}{324}$$
and
$$log(5)>\frac{13688}{8505}$$
An upper bound for $\log(2)$ may be taken from the Dalzell-type integral $$\int_0^1 \frac{x^3 (1 - x)^3}{8 (1 + x)} dx = \frac{111}{160} - \log(2)$$
so $$log(2)<\frac{111}{160}$$
The resulting stricter inequality
$$\frac{22}{7} < \frac{355}{324} + 3\frac{13688}{8505}-4\frac{111}{160}$$
is easily verified, thus proving
$$e^\pi < \frac{15\pi}{2} $$