I'd like to prove that if there exists an order isomorphism $F:\left\langle \mathcal{P}\left(A\right),\subseteq\right\rangle \to\left\langle \mathcal{P}\left(B\right),\subseteq\right\rangle $ for some nonempty $A$ and $B$ then there must be some $f:A\to B\ $ S.T. $F$ is defined by $F:X\mapsto\left\{ f\left(x\right)\mid x\in X\right\} $
My thought was to explicitly build $f$ out of $F$ by defining $f\left(x\right)=F\left(\left\{ x\right\} \right)$, which would work exactly as requested. However, I'm having trouble proving that $F$ must take singletons to singletons. I suspect that in general, $F$ must preserve cardinality, but I was not successful in proving this.
Hint: Singleton sets are the minimal nonzero elements of $\mathcal{P}(X)$ (and $\mathcal{P}(Y)$). Then define $f$ in such a way that $\left\{f(x)\right\}=F(\left\{x\right\})$, as you wanted.