While expressions of the form $a/bc$ are definitely ambiguous, since they can be interpreted either as $(a/b)c$ or as $a/(bc)$, what about expressions of the form $a-b-c$ or $a/b/c$?
"Subtraction" and "Division" are certainly not associative, so that, for example, if we interpret $1-1-1$ to mean $(1-1)-1$ then we get $-1$, but if we interpret it as $1-(1-1)$, we get 1.
Similarly, if we interpret $8/2/2$ as $(8/2)/2$, then we get $2$ whereas if we interpret it as $8/(2/2)$ then we get $8$.
Computers, of course will evaluate from left to right, so in that case, $1-1-1$, to a computer is equal to $-1$ and $8/2/2$ is equal to $2$.
The way I see this, subtraction and division aren't legitimate binary operations because they aren't associative, so I would say that $1-1-1$ should be interpreted as $1+(-1)+(-1)$, which agrees with the "left-to-right" rule. Is there a definite answer here, or is it just a matter of ambiguous notation?
Subtraction and addition are done left-to-right (and simultaneously). Multiplication and division aren't, and are ambiguous if there is any division which isn't the rightmost operation.
I am not aware of any real reason for this discrepancy other than successive subtractions being much more common (for instance with polynomials), and there not being any real notational alternative (no fraction-like notation for subtraction, for instance), so having a fixed convention for subtraction is a lot more important than for division.