In Alessandro Sisto's notes on geometric group theory he mentions that "Many, probably most people in the field" believe that not all $\delta$-hyperbolic groups are CAT(0) groups. Can anything be said as to why this would be the suspicion? It seems completely reasonable to me that some CAT(0) (or dare I say CAT(-1)?) space could be cooked up for any given $\delta$-hyperbolic group.
Are there specific examples of hyperbolic groups for which a reasonable effort has been given to show that they are (or are not) CAT(0) without avail? Or are most hyperbolic group's CAT(0) statuses known?
I think Sapir's group $$ G:=\langle a, b, t; a^t=ab, b^t=ba\rangle $$ is the group you are looking for. Sapir and Drutu claimed (originally citing a result of I. Kapovich but then stating that Minasyan had a proof) that $G$ is hyperbolic, but suggested that it might not be linear (1), (2). They posed this problem in about 2004, and (last time I checked!) this question was still a talking point among geometric group theorists. If I recall correctly, the question of whether it was $\operatorname{CAT}(0)$ was also asked*. In 2013, Button provided the first proof in the literature that this group is hyperbolic, and although he proves that certain similar groups are $\operatorname{CAT}(0)$ he does not show that Sapir's group is $\operatorname{CAT}(0)$ (3). Note that Sapir's group is residually finite (ascending HNN-extensions of free groups are always residually finite).
Another group to consider is a group of M. Kapovich. He constructed a hyperbolic group which is not linear. The paper, allegedly, is this one. However, after a quick flick through, I am having trouble finding this specific result. I do not know if M. Kapovich's group is $\operatorname{CAT}(0)$ or not (and, to be honest, having glanced through the paper it probably is $\operatorname{CAT}(0)$), but it is worth contemplating.
*Certainly I remember at a conference in summer 2012 trying to naively prove that $G$ was $\operatorname{CAT}(0)$, to no avail!