An elementary embedding is an injection $f:M\rightarrow N$ between two models $M,N$ of a theory $T$ such that for any formula $\phi$ of the theory, we have $M\vDash \phi(a) \ \iff N\vDash \phi(f(a))$ where $a$ is a list of elements of $M$.
A critical point of such an embedding is the least ordinal $\alpha$ such that $f(\alpha)\neq\alpha$.
A large cardinal is a cardinal number that cannot be proven to exist within ZFC. They often appear to be critical points of an elementary embedding of models of ZFC where $M$ is the von Neumann hierarchy, and $N$ is some transitive model. Is this in fact true for all large cardinal axioms?
No. If $\kappa$ is the critical point of a full elementary embedding $j : V\to N$, with $N$ transitive, then $\kappa$ is measurable. Yet not all large cardinals are measurable; see, for instance, weakly compact cardinals. Even large cardinals with higher consistency strength (like Woodin cardinals) are not always measurable.