Let $A$ be an $n \times n$ real matrix with $\det A \ge 0$. Denote by $\sigma_i$ the singular values of $A$.
Does there exist a permutation $\alpha \in S_n$ such that $A_{ii} \le \sigma_{\alpha(i)}$ for every $1 \le i \le n$?
I am particularly interested in the case where $n=2$.
No, think of $\begin{pmatrix}N+1 & N \\ N & N+1\end{pmatrix}$; one eigenvalue (and singular value) is $1$ but diagonal entries are big.