Suppose $F : C \rightarrow D$ is a full and faithful functor from $C$ to $D$.
Clearly, this does not imply that $F : \text{Ob}(C) \rightarrow \text{Ob}(D)$ is surjective.
Question: But does this imply that $F : \text{Ob}(C) \rightarrow \text{Ob}(D)$ is injective?
The answer is no. A minimal example would be the following: let $D$ be the category with only one object $X$, and only one morphism (the identity of $X$). Now, let $C$ be the category with two objects $Y$ and $Z$, and only four morphisms: the identity of $Y$, that of $Z$, a morphism $f:Y\to Z$ and a morphism $g:Z\to Y$, such that $f$ and $g$ are inverse to each other.
Define a functor $F:C\to D$ by $F(Y)=F(Z) = X$, and all morphisms are sent by $F$ to the identity of $X$. Then $F$ is fully faithful (it is even an equivalence of categories), but is not injective on the sets of objects.